Porphyrazine group

The Porphyrazine Group focuses on the synthesis and study of physico-chemical properties of porphyrazines and their analogues.  Special attention is given to heterocyclic analogues of phthalocyanines – porphyrazines containing fused heterocyclic fragments, such as 1,2,5-chalcogenodiazole, pyrazine, 1,4-diazepine.

The Head of the group - Professor Pavel A. Stuzhin

Curriculum Vitae

 Recent selected publications 

  1. Stuzhin, P. A.; Nefedov, S. E.; Kumeev, R. S.; Ul-Haq, A.; Minin, V. V.; Ivanova, S. S. 
    Effects of Solvation on the Spin State of Iron(III) in 2,8,12,18-Tetrabutyl-3,7,13,17-tetramethyl-5,10-diazaporphyrinatoiron(III) Chloride
    Inorg. Chem. 2010, 49(11), 4802-4813.
    DOI: 10.1021/ic9012075
  2. Stuzhin, P. A. Ul-Haq, A.; Nefedov, S. E.; Kumeev, R. S.; Koifman, O. I.
    Synthesis and Study of the Binuclear m-Oxodiiron(III) Complexes of 5-Monoaza- and 5,15-Diazasubstituted b-Octaalkylporphyrins
    Eur. J. Inorg. Chem. 2011, 16, 2567-2578.
    DOI: 10.1002/ejic.201100112
  3. Tarakanov, P. A.; Donzello, M. P.; Koifman, O. I.; Stuzhin, P. A.
    Porphyrazines with Annulated Diazepine Rings. 3. MgII Complex of 4-tert-Butylphenyl Substituted Tetra(1,4-diazepino)porphyrazine: Synthesis and Peculiar Effect of Solvent on Its Spectral Properties
    Macroheterocycles 2011, 4(3), 177-183.
    DOI: 10.6060/mhc2011.3.06
  4. Ivanova, S. S., Stuzhin, P. A.
    Indium(III) complexes of octaphenylporphyrazine: Effect of halide coordination on the basic properties and stability in acid media
    J. Porphyrins Phthalocyanines 2011, 15(11-12), 1299-1309.
    DOI: 10.1142/S108842461100421X      
  5. Stuzhin, P. A.; Mikhailov, M. S.; Travkin, V. V.; Gudkov, E. Y.; Pakhomov, G. L.
    Multilayer Photovoltaic Structures Based on Tetrathiadiazoloporphyrazine/Subphthalocyanine Heterojunction
    Macroheterocycles 2012, 5(2), 162-165.
    DOI: 10.6060/mhc2012.120573p
  6. Stuzhin, P. A.; Ivanova, S. S.; Dereven’kov, I.; Makarov, S. V.; Silaghi-Dumitrescu, R.; Homborg, H.
    First Water-Soluble µ-Nitrido Dimer of Iron Phthalocyanine
    Macroheterocycles 2012, 5(2), 175-177.
    DOI: 10.6060/mhc2012.120360s
  7. Stuzhin, P. A.; Tarakanov, P.; Shiryaeva, S.; Zimenkova, A.; Koifman,O. I.; Viola, E.; Donzello, M. P.; Ercolani, C.
    Porphyrazines with annulated diazepine rings. 4. Synthesis and properties of MgII tetradiazepinoporphyrazine carrying exocyclic styryl fragments
    J. Porphyrins Phthalocyanines 2012, 16(7), 968-976.
    DOI: 10.1142/S1088424612501052
  8. Stuzhin, P A.; Mikhailov, M. S.; Yurina, E. S.; Bazanov, M. I.; Koifman, O. I.; Pakhomov, G. L.; Travkin, V. V.; Sinelshchikova, A. A.
    First tellurium-containing phthalocyanine analogues: strong effect of tellurium on spectral, redox and conductivity properties of porphyrazines with annulated chalcogenodiazole ring(s)
    Chem. Comm. 2012, 48 (81), 10135 – 10137.
    DOI: 10.1039/c2cc35580a
  9. Stuzhin, P. A.; Goryachev, M. Yu.; Ivanova, S. S.; Nazarova, A.; Pimkov, I.; Koifman, O I.
    Perfluorinated porphyrazines 1: Synthesis and UV-vis spectral study of perfluorinated octaphenylporphyrazine and its indium(III) complex, [MPA(F5Ph)8](M = 2H, InIII(OH))
    J. Porphyrins Phthalocyanines 2013, 17(8-9), 905-912.
    DOI: 10.1142/S1088424613500892
  10. Stuzhin, P.A.
    Fluorinated Phthalocyanines and Their Analogues
    In: Fluorine in Heterocyclic Chemistry, Volume 1. 5-Membered Heterocycles and Macrocycles/ Edited by G. G. Nenajdenko. Heidelberg: Springer, 2014. P. 621- 681.
    DOI: 10.1007/978-3-319-04346-3_15
  11. Kozlov, A. V.; Stuzhin, P. A.
    New Porphyrazinoid Containing Pyrazine in Place of One Pyrrole Ring
    Macroheterocycles 2014, 7(2), 170-173.
    DOI: 10.6060/mhc140270s
  12. Stuzhin, P. A.; Ivanova, S. S.; Koifman, O. I., Petrov, O. A., Nazarova, A.
    On the synthesis and properties of the MgII complex of perfluorinated octaphenylporphyrazine
    Inorganic Chemistry Communications 2014, 49, 72-75.
    DOI: 10.1016/j.inoche.2014.09.002
  13. Ivanova, S. S.; Moryganova, Yu.; Hamdoush, M.; Koifman, O. I.; Sal’nikov, D. S.; Stuzhin, P. A.
    Phosphorus(V) Tetrapyrazinocorrolazines - First Corrolazine Derivative with Fused Heterocyclic Rings
    J. Porphyrins Phthalocyanines 2014,
    DOI: 10.1142/S1088424614500679
  14. Svec, J.; Zimcik, P.; Novakova, L.; Rakitin, O. A.; Amelichev, S.; Stuzhin, P. A.; Novakova V.
    1,2,5-Chalcogenodiazole-Annulated Tripyrazinoporphyrazines: Synthesis, Spectral Characteristics and Influence of the Heavy Atom Effect on their Photophysical Properties
    Eur. J. Organic Chemistry 2014,
    DOI: 10.1002/ejoc.201403329